Hi,
Autumn WindI am a Scorpion girl and I would say I had the most amazing time with him.The most snesuos,caring and loving.
The only problem was his indecisiveness for a major decision about marriage.As a scorpio we like something permanent.Besides that he lied me many a times.So don't lie to your Scorpio,love him whole heartedly and don't ever in front of him by mistake also doo anything to make him jealous.As my Libran guy did tried to make jealous purposely so that he can get my attention.
You might find that Scorpios are bit ruthless and not that soft hearted as Librans and sometimes you might think them insane.They will not like to share many things as they are born secretive,even if they are in problems as it makes them look weak.At that time don't ask too many question or panic just be there and help by being there.I am surre your presencce will count.
As far as I know Libra-Scorpio is a great combination but only thing is there are few things which both needs to understand.
Don't try to change the decision made by Scorpio,as wether you approve or not it will not matter.
I wish you good luck and I think love co-operation and Understanding can really help in this relationship.